Abstract
The effects of experimental conditions (counterflow-rate, magnitude of the constant electric current, and difference between mobilities of leading and terminating electrolytes) on the quality of isotachophoretic separation has been investigated using thermometric detection. As with chromatographic techniques, the central moment of the second order computed by an analogue computer was chosen as the mathematical expression of the quality of separation. The effect of heat transfer through the capillary wall is discussed.
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