Abstract
Two new coordination polymers (CPs), [Mn(H2L)]n (1) and [Mn(H2L)(H2O)2]n (2) (H4L= 5,5′-(ethene-1,2-diyl)diisophthalic acid), have been synthesized under different temperature. 1 is a 3D (6,6)-connected framework built by infinite O-Mn-O-C-O-Mn- chains and H2L2− linkers. 2 has a 2D (4,4)-connected network structure formed by metal-chain. 2 obtained at higher temperature than of 1, which will induce a 3D architecture. The results indicated that the hydrothermal reaction temperature may affect on the structure of the CPs 1 and 2 in this system. The magnetic behaviors of the complexes have been investigated in detail in CPs 1 and 2.
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