Abstract

Colour temperatures measured on photoflash powders are higher than expected from theoretical calculations Determinations of the true temperature of stationary flames of aluminium flakes suspended in air have been made (a) by a line reversal method and (b) by measuring the absolute light intensity. The experimental values obtained were very close to the theoretical flame temperature of about 3,000° C., that is, the boiling point of the oxide An explanation is offered for the difference between the true temperature and colour temperature for flames containing incandescent particles, the reason being the small size of the radiant particles, which introduce optical anomalies. It is concluded therefore to be unprofitable to measure the colour temperature at all as this has no relation to the true temperature. Magnesium behaved very similarly, the true temperature being the melting point of MgO, near 2,800° C, whereas the colour temperature is above 3,900° K. The two-colour method of Hottel and Broughton for temperature measurements in hydrocarbon flames is examined in the light of this experience.

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