Abstract

The temperature-dependent crack growth resistance behavior of the lead-free (1−x)Ba(Zr0.2Ti0.8)O3–x(Ba0.7Ca0.3)TiO3 (x=0.385) ceramic was characterized using compact-tension specimens from 25°C to 60°C. The observed plateau fracture toughness at 25°C was found to be approximately 37% lower than commercial Pb(Zr,Ti)O3. At elevated temperature, the maximum fracture toughness displayed a decrease, which was found to be related to the temperature-dependent elastic and ferroelastic properties. Mechanical measurements are presented that demonstrate decreasing effective switching strain, coercive stress and Young’s modulus with increasing temperature.

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