Abstract
Study on the volumetric and compressibility properties of citrate salts trilithium citrate (TLC) and triammonium citrate (TAC) in (0.005, 0.01, 0.03 and 0.05)molkg−1 aqueous solutions of ionic liquid [C4mim][BF4] at 5K intervals, from 288.15K to 308.15K and experimental pressure p=0.1MPa, are performed to understand the intermolecular interactions existing in the system. We have utilized the experimental data of density and speed of sound for determining the apparent molar and partial molar parameters concerning volumetric and compressibility properties at the investigated temperatures. The structure making or breaking ability of ionic liquid has been discussed in terms of sign of (∂2Vϕ0/∂T2). Other parameters like partial molar volumes of transfer and partial molar isentropic compression of transfer demonstrate in terms of hydrophilic- hydrophilic, hydrophilic-hydrophobic, hydrophobic-hydrophobic interactions. Fourier transform infrared spectroscopy (FTIR) was employed to acquire information about the interaction between the citrate salts (TLC, TAC) and ionic liquid [C4mim][BF4]. The results have been discussed in terms of interactions existing among citrate salts and ionic liquid solutions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
