Temperature dependent magnetic, dielectric and Raman studies of partially disordered La2NiMnO6

Abstract

We report a detailed magnetic, dielectric and Raman studies on partially disordered and biphasic double perovskite La2NiMnO6. DC and AC magnetic susceptibility measurements show two magnetic anomalies at TC1~270K and TC2~240K, which may indicate the ferromagnetic ordering of the monoclinic and rhombohedral phases, respectively. A broad peak at a lower temperature (Tsg~70K) is also observed indicating a spin-glass transition due to partial anti-site disorder of Ni2+ and Mn4+ ions. Unlike the pure monoclinic phase, the biphasic compound exhibits a broad but a clear dielectric anomaly around 270K which is a signature of magneto-dielectric effect. Temperature-dependent Raman studies between the temperature range 12–300K in a wide spectral range from 220cm−1 to 1530cm−1 reveal a strong renormalization of the first as well as second-order Raman modes associated with the (Ni/Mn)O6 octahedra near TC1 implying a strong spin–phonon coupling. In addition, an anomaly is seen in the vicinity of spin-glass transition temperature in the temperature dependence of the frequency of the anti-symmetric stretching vibration of the octahedra.