Abstract

ABSTRACTThe temperature dependent local structure of BaTiO3 single crystal was investigated by Synchrotron X-ray Absorption Spectroscopy (XAS) technique. From the X-ray Absorption Near-Edge Structure (XANES) measurements at Ti K-edge, it was seen that the local structure around Ti atom gradually changed with increasing temperature, showing the phase transition from tetragonal to cubic. A comparison between the measured and calculated XANES spectra revealed the gradual change of local structure as a result of the decreasing c/a ratio.

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