Abstract

This paper reports an improvement in Pt/n-GaN metal-semiconductor (MS) Schottky diode characteristics by the introduction of a layer of HfO2 (5 nm) between the metal and semiconductor interface. The resulting Pt/HfO2/n-GaN metal-insulator-semiconductor (MIS) Schottky diode showed an increase in rectification ratio from 35.9 to 98.9(@ 2V), increase in barrier height (0.52 eV to 0.63eV) and a reduction in ideality factor (2.1 to 1.3) as compared to the MS Schottky. Epitaxial n-type GaN films of thickness 300nm were grown using plasma assisted molecular beam epitaxy (PAMBE). The crystalline and optical qualities of the films were confirmed using high resolution X-ray diffraction and photoluminescence measurements. Metal-semiconductor (Pt/n-GaN) and metal-insulator-semiconductor (Pt/HfO2/n-GaN) Schottky diodes were fabricated. To gain further understanding of the Pt/HfO2/GaN interface, I-V characterisation was carried out on the MIS Schottky diode over a temperature range of 150 K to 370 K. The barrier height was found to increase (0.3 eV to 0.79 eV) and the ideality factor decreased (3.6 to 1.2) with increase in temperature from 150 K to 370 K. This temperature dependence was attributed to the inhomogeneous nature of the contact and the explanation was validated by fitting the experimental data into a Gaussian distribution of barrier heights.

Highlights

  • Attempts to sustain Moore’s law[1] have been spearheaded by continuous scaling of Si transistors for over 30 years

  • This paper reports an improvement in Pt/n-gallium nitride (GaN) metal-semiconductor (MS) Schottky diode characteristics by the introduction of a layer of HfO2 (5 nm) between the metal and semiconductor interface

  • We believe that HfO2 would play a positive role as an interfacial layer in GaN based Schottky diodes and it is important to understand the electrical properties of this Pt/HfO2/n-GaN interface to enable us to better utilise the possibilities offered by the combination of high-k dielectrics and III-nitride semiconductors

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Summary

INTRODUCTION

Attempts to sustain Moore’s law[1] have been spearheaded by continuous scaling of Si transistors for over 30 years. Schottky diodes[7] have advantages like high operating frequency, fast switching speed and low forward voltage drop. Schottky diodes are widely used in a variety of RF and microwave applications like varactors, detectors, mixers, multipliers and low-voltage reference circuits. There have been various studies on the metal-insulator-semiconductor Schottky barrier[8,9,10,11] in particular due to the advantages it offers like lower leakage current and higher rectification ratio. In the study of semiconductor surfaces, the metal-insulator-semiconductor Schottky diode is an important device. The GaN MIS structure has been studied[12,13,14,15] for its importance in switching devices where the presence of the insulator layer would provide lower leakage currents and reduce power consumption

Why HfO2 for GaN Schottky?
EXPERIMENTAL
Material characterisation
Electrical characterisation
CONCLUSIONS
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