Abstract

Temperature dependence of corrosion behaviour in simulated wet storage conditions for spent nuclear fuels were investigated systematically by comparing SAM2X5 amorphous steel and 316 L SS. Results indicated that with elevating temperature, the passive current for the amorphous steel increased distinctly but without pitting corrosion. The sensitivity of the passive current with temperature for the amorphous steel was related to the reduction of Cr2O3 content and altered semiconductor characteristics for its passive film, and the prominent pitting resistance at higher temperatures was associated with the remarkably inhibited pit initiation by the uniform passive film and the suppressed stable growth of metastable pits.

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