Abstract
The 13C relaxation times and nuclear Overhauser enhancements of the protonated carbons in 1,3,5-tribromobenzene were measured as a function of temperature in the solvent benzene- d 6. Rotational correlation times, τ C(CH), calculated by the Microviscosity/Free Rotor and Hu-Zwanzig “slip” models are substantially below the measured values. In contrast, correlation times predicted by the Hynes—Kapral—Weinberg model are in near quantitative agreement with experiment at all temperatures studied.
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