Abstract
Temperature dependence of the photoinduced charge transfer process in Rb0.94Mn[Fe(CN)6]0.98·0.2H2O was investigated by observing the pair valence states of adjacent metal ions by Raman spectroscopy. After irradiation by 395 nm light in resonance with ligand-to-metal charge transfer band (CN- → Fe(III)), the photoinduced phase containing low-temperature-like phase was generated as a result of the charge transfer from Mn(II) to Fe(III). Since this process was suppressed upon cooling, it was suggested that the charge transfer process was assisted by a thermal-activated process.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
