Abstract
AbstractThe nuclear magnetic resonance of 133Cs in a CsMnCl3 single crystal grown by the Czochralski method has been investigated by employing a Bruker FT NMR spectrometer. The resonance lines of two different Cs(I) and Cs(II) were recorded. The quadrupole coupling constants of Cs(I) and Cs(II) in CsMnCl3 decrease as the temperature increases. The temperature dependence of e2qQ/h is explained with a single torsional frequency of the Cs‐Cl ion by means of the simple Bayer theory. Also, we have investigated the transferred hyperfine interaction due to the transfer of spin density from the Mn2+ ion to the Cs+ ion in the CsMnCl3 single crystal using the magnetic susceptibility and the paramagnetic shift using nuclear magnetic resonance.
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