Temperature Dependence of GaAs1-xBix Band Gap Studied by Photoreflectance Spectroscopy

Abstract

We performed photoreflectance (PR) spectroscopy in order to investigate the fundamental band gap of GaAs1-xBix alloys. The temperature dependence of the band gap energy was evaluated by analyzing of the Franz–Keldysh oscillation in the PR spectra. With increasing Bi content, the band gap energy of GaAs1-xBix alloy is reduced, which shows a large optical bowing. The temperature coefficient of the band gap decreases appreciably in alloys with increasing Bi content. For x=0.026, the temperature coefficient near room temperature is -0.15 meV/K which is 1/3 of the value for GaAs.