Abstract
1. The kinetics of the alkaline hydrolysis of substituted phenyl thionophosphinates and acetates has been studied. The activation parameters were calculated, and their dependence on the structure of the leaving group of the esters and the composition of the medium has been analyzed. 2. Polylinear regression dependences were obtained, which show the influence of all the experimentally controlled factors on the hydrolysis of esters (I) and (II). It was concluded that the detailed mechanisms of the alkaline hydrolysis of thionophosphinates and acetates in mixtures of water with acetonitrile are similar.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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