Abstract
Recent experiments have reported measurements of rainbow scattering features in the angular distributions of hyperthermal Ar colliding with LiF(001) [Kondo et al., J. Chem. Phys. 122, 244713 (2005)]. A theory of atom–surface collisions recently developed by the authors, based on the eikonal approximation, that includes multiphonon energy transfers is used to explain the temperature dependence of the measured scattered angular distribution spectra.
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