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Abstract
1. The products of the radical telomerization of vinyl chloride with FSO2CF2I, i.e., the telomers FSO2CF2(CH2CHCl)nI with n=1–3, have been isolated. 2. At 90°C ordinary telomerization is accompanied to a considerable extent by stepwise telomerization; however, at 60°C the contribution of the secondary reactions to the formation of the homologous telomers is insignificant. 3. The partial chain-transfer constants to FSO2CF2I for FSO2CF2(CH2CHCl)n (n=1–3) radicals at 60°C have been determined.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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