Abstract
The telomerization of ethylene and carbon tetrachloride is initiated by various amines in the absence of metallic salts in the stainless steel autoclave. In this reaction the initiating efficiency of amines depends upon their basicity and chemical structure. In general, strong bases are excellentn initiators but the strength of the basicity of amines gives only a small effect on the composition of the telomer produced. The temperature of the reaction and the dielectric constant of the solvent have pronounced effects on this reaction process. And from these observation and the other experiments, the distinction between the present initiating system and the redox system of amine-metallic salt was discussed on the basis of the reaction mechanism involved.
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