Technical-environmental optimisation of the activated carbon production of an agroindustrial waste by means response surface and life cycle assessment.

Abstract

In this study, a simultaneous optimisation of technical and environmental parameters for activated carbon production from soybean shells is presented. A 23 factorial design was developed to explore the performance of the technical responses yield and iodine number, and the single score of ReCiPe endpoint method, which was evaluated by means the life cycle assessment. The independent factors included in the design of experiments were the impregnation ratio, temperature, and time activation. Three quadratic equations were obtained and simultaneously optimised by maximisation of the overall desirability function. The principal results of the individual responses indicate that the iodine number is practically independent of the activation temperature in a range of 450 ºC-650 ºC; the yield is inversely proportional to activation time and exhibits minimum values between 500 ºC-600 ºC; and the environmental response single score presents the lowest value at a temperature and time activation of 450 ºC and 30 min, respectively. The most polluting stage of activated carbon production from soybean shells production is the impregnation stage, mainly for the use of ZnCl2 as activating agent and the energy consumption. The simultaneous optimisation of the three responses indicates that the optimal activated carbon should be produced at 180 min, 650 ºC, and an impregnation ratio of 1 g soybean shell g ZnCl2-1.