Abstract

The optical schemes and characteristics of atomic absorption Hg <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0</sup> analyzers based on the Zeeman effect and a low-pressure capillary mercury lamp, as well as on 190 fm linewidth UV dye laser systems have been studied in detail. The method of evaluating the limit of detection (LOD) of atomic absorption analyzers is proposed. The characteristics of modern ultra-narrowband sensors and sources of UV radiation are analyzed. The efficiency of using new thermal ultrasonic sensors as optical power detectors in the atomic absorption analyzer is discussed. Technical characteristics and reliability of such sensors are compared with all known thermal sensors. The main physical and technical limitations that have a negative effect on the sensitivity and miniaturization of thermal ultrasound sensors are presented. The study shows that such thermal sensors have low sensitivity and accuracy, which makes their use in portable express analyzers of background mercury impractical. The evaluation results prove that the analyzers which use a transverse magnetic field for splitting the lamp emission line also cannot register background mercury concentration. This fact is explained by the low signal-to-noise ratio (SNR) of the discharge low-pressure UV lamp operating in a continuous mode and by the absorption of forbidden oxygen lines by the reference optical signal. The estimation results shown that the portable Hg <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0</sup> analyzers based on UV dye laser systems can reach the LOD <; 0.1 ng/m <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sup> . Thus, the main stage in the design of the portable express background mercury analyzers is a measurement of the SNR of UV sources and sensors.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.