Tear strength and tensile strength of model filled elastomers

Abstract

AbstractMeasurements have been made of the tear strength, tensile strength, and energy dissipated during stretching for model filled elastomers consisting of polybutadiene with glass beads incorporated. The glass beads were pretreated with various silanes, some of which could, in principle, form covalent bonds with the polybutadiene matrix during free‐radical crosslinking of the latter and some of which could not. The tear strength of the elastomer was increased by the addition of glass beads, by about 25% for the largest beads, having a mean diameter of 150μm. This effect is attributed to increased roughness of the tear path. The breaking elongation in tension was reduced by the addition of glass beads but the breaking stress was only seriously reduced for the least‐well‐adhering beads. The stored strain energy density at break was reduced in all cases. This is attributed to large glass beads acting as fracture nuclei in tension. Calculated sizes of a Griffith crack, 150–300 μm, are consistent with this hypothesis. Strain energy dissipated due to dewetting was found to be in the range 4–13% of the input energy, depending upon the degree of interfacial adhesion, in addition to about 10% dissipated in the unfilled material. The maximum value observed is in reasonable agreement with theoretical predictions.