Abstract

Organometallics One major reason why transition metals are good catalysts is that they can shuttle between oxidation states. This flexibility lets them slide in and out of chemical bonds; so, for instance, they can snip a bond between carbon and boron and then stitch a carbonfluorine bond in its place. Planas et al. now report that bismuth can also orchestrate such bond-swapping events. They implement a fully catalytic cycle for fluorination of aryl boronates, in which bismuth hops between its +3 and +5 oxidation states. Science , this issue p. [313][1] [1]: /lookup/doi/10.1126/science.aaz2258

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