Abstract

A modified graphite felt (MGF) was prepared with carbon black (CB) and polytetrafluoron (PTFE) for cathodic electrochemical H2O2 production, which was used in a flow-through cathodic electro-Fenton reactor to degrade chlorinated hydrocarbons. Cathode electrode was floating on aqueous surface and 369.1 mg/L H2O2 could be produced after 1 h 150 mA power applied without O2 aeration. The main O2 source for H2O2 production was confirmed from air with this floating position. In a 2.0 L flow-through cathodic electro-Fenton system, 95.97 % degradation efficiency for 5.0 mg/L trichloroethylene (TCE) was achieved in 90 min with 13.4 mL/min influent rate. Reducing the reactor volume to 0.14 L, 5.0 mg/L TCE could be degraded completely in 10 min with continuous 4 L influent. The mixed chlorinated hydrocarbons (TCE, cis-1,1-dichloroethylene, 1,2-dichloroethane, and dichloromethane) were also rapidly degraded in 20 min. The flow-through cathodic electro-Fenton reactor presented excellent degradation ability for chlorinated hydrocarbons with a smaller volume. In the simulated sand tank system, after continuously operated 27 days, H2O2 concentration in electrode well was still remained at 80 mg/L. In the contaminated field in Tianjin, China, H2O2 yield of MGF in groundwater could keep at about 60 mg/L after 220 min operating.

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