Taxonomic characterisation of fresh Dipterocarpaceae resins by gas chromatography–mass spectrometry (GC–MS): providing clues for identification of unknown archaeological resins

Abstract

Plant and particularly non-wood forest products have played an important role in the evolution of human cultures all over the world, as source of food but also of raw substances fulfilling material, spiritual, and medicinal requirements. Plant exudates and particularly dammar resins (Dipterocarpaceae family) were widely used in the past in Asia notably as waterproofing and caulking materials. This study focuses on the GC–MS chemical characterisation of freshly collected dammars and establishes new molecular parameters enabling discrimination between dammars and other types of plant resin, whatever their botanical origin. Such analyses provide clues for a precise identification (taxonomy, occurrence of other material in addition to the resin, alteration state) of unknown resinous material discovered in archaeological contexts. The value of our approach is illustrated by the taxonomic characterisation of two samples collected in jars from the Brunei wreck and a Chinese junk lost more than 40 km off the Sultanate of Brunei during the end of the fifteenth century or the early beginning of the sixteenth century.