Tannic acid etched ZIF-8 incorporated thin-film nanocomposite nanofiltration membrane with enhanced performance

Abstract

Incorporating functionalized nanomaterials in the selective layer of conventional polyamide nanofiltration (NF) membrane is a promising strategy for overcoming the trade-off between permeability and selectivity. Highly hydrodispersible TA/ZIF-8 composite nanomaterials were prepared by etching ZIF-8 with tannic acid, and the thin-film nanocomposite (TFN) NF membranes were prepared by introducing TA/ZIF-8 into the interfacial polymerization aqueous phase solution. The nanomaterials and NF membranes' structure, chemical composition, and hydrophilicity were comprehensively characterized. The influence and mechanism of introducing TA/ZIF-8 into the polyamide layer on the separation performance of the TFN membranes were discussed by separating typical mono- and divalent salts. The optimal TFN membrane had a water flux of 26.59 LMH-bar−1 (increased by 86.6% than that of the TFC-blank membrane) with 94.95% rejection of Na2SO4 while having good antifouling performance and stability. Furthermore, the inverse size exclusion phenomenon of chlorine-contained salts was explored through relevant control experiments. This work is valuable for expanding the application of 3D nanomaterials in membrane separation technology and preparing high-performance TFN nanofiltration membranes.