Abstract
A hetero-bimetallic Pd–Ru N-Heterocyclic Dicarbene (NHDC) complex was synthesized from a Ag–Ru complex by transmetalation. The Pd–Ru system displays high catalytic activity in tandem Suzuki–Miyaura cross-coupling/transfer hydrogenation reaction of bromoaryl ketones with boronic acids in toluene and 2-propanol in the presence of KOH.
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