Abstract

Tandem solar cell provides an effective way to improve power conversion efficiency of organic solar cell by combining two or more organic solar cells. Each cell has different absorption maximum and width so it provides the amenities of using the photon energy more effectively. Due to the limited absorption band of organic materials, single junction organic solar cells suffer from low efficiency. Here, we demonstrate the performance of single layer devices based on the solution of carrier continuity equation in MATLAB. Polymers P3HT:PCBM, pBBTDPP2:PCBM and PCDTBT:PCBM provide power conversion efficiency of 3%, 3.15% and 6.2% respectively. Hence series connected tandem cell P3HT:PCBM as front cell and pBBTDPP2:PCBM as rear cell is designed to achieve higher efficiency where the proposed model gives the power conversion efficiency of 6%. A major back through came when the front cell is replaced by PCDTBT:PCBM solar cell in the device configuration which provides the power conversion efficiency of 8.8%, till now the maximum efficiency for organic solar cell.

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