Abstract
A new catalytic enantioselective tandem deoxygenation/aza‐Diels‐Alder reaction of nitrones with enecarbamates was serendipitously discovered in the presence of chiral copper(II) diphosphate complexes. This process affords a wide range of 4‐aminotetrahydroquinolines in respectable yields under mild conditions with good to excellent ee values.
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