Abstract

The friction and wear behaviors of plasma-sprayed yttria-stabilized zirconia (YSZ) coatings against Si3N4 and Al2O3 were evaluated from 25 °C to 800 °C in air. As the temperature increased, refined grains with severe lattice distortion and the phase transition from monoclinic to tetragonal were present within the wear track of the YSZ coating during friction. When the YSZ coatings were rubbed against Si3N4 and Al2O3 counterparts, all the worn samples showed common wear characteristics of fracture and fragmentation near the sliding surface. The wear discrepancy between the two tribo-pairs was due to the differences in tribo-induced interactions. In particular, TEM clarified the intense amorphization at the superficial regions of the YSZ coating when rubbed against Si3N4, which resulted in better wear resistance of the YSZ/Si3N4 sliding couple. The computational simulation using the semi-analytical model revealed higher contact temperatures and Von Mises stresses for the YSZ/Si3N4 sliding couple, which aided the amorphization of the regions near the sliding areas. Nevertheless, the higher normal stress between the YSZ/Al2O3 contacts caused cracking and localized fracture, leading to severe wear.

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