Tailoring the photo-Fenton activity of nickel ferrite nanoparticles synthesized by low-temperature coprecipitation technique

Abstract

Nanosized inverse spinel ferrites are the most captive class of materials, which have significantly amplified the attention of the researchers due to their vital properties. An undemanding and economically viable co-precipitation technique was used to synthesize nickel ferrite (NiFe2O4) nanoparticles in order to investigate structural, optical, magnetic and electrical properties. X-Ray diffraction studies confirmed that the synthesized NiFe2O4 nanoparticles had a cubic spinel structure. In Fourier Transform Infrared spectra, two primary absorption bands at 561cm−1 and 453cm−1 were observed. Particle size was evaluated using High Resolution Transmission Electron Microscopy and found to be in the range 15–18nm. UV–vis spectral analysis and Photoluminescence reveal the optical property of nickel ferrite nanoparticles. Using Kubelka-Munk plot bandgap is found out to be 2.66eV and the excitation wavelength shows the recombination of electrons and holes. The retentivity and coercivity were estimated to be 5.4318emu/g and 1170G using vibrating sample magnetometer at room temperature (303K). The photocatalytic application for the synthesized sample was studied for degradation of Methylene blue dye which was monitored using spectrophotometer at regular intervals of time and the mechanism for degradation has been proposed involving OH radical as an oxidant.