Abstract

Polymer solutions with different concentrations of SU-8 2002/poly(ethylene) glycol/tetrabutyl ammonium tetrafluoroborate (SU-8/PEO/TBATFB) were electrospun in a low-voltage near-field electrospinning platform (LVNFES) at different velocities. Their diameters were related to the concentration contents as well as to their Deborah (De) numbers, which describes the elasticity of the polymer solution under determined operating conditions. We found a direct correlation between the concentration of PEO/TBATFB, the De and the diameter of the fibers. Fibers with diameters as thin as 465 nm can be achieved for De ≈ 1.

Highlights

  • There are two well-known processes to obtain electrospun fibers, the near-field electrospinning (NFES) and the far-field electrospinning (FFES)

  • The polymer system consisted of a SU-8 2002 (SU-8)/poly(ethylene) oxide (PEO) solution with tetrabutylammonium tetrafluoroborate (TBATFB) as additive to increase the conductivity of the solution

  • SU-8 was obtained from MicroChem (Newton, MA, USA), while PEO and TBATFB of 99% purity were obtained from Sigma–Aldrich (Saint Louis, MI, USA)

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Summary

Introduction

There are two well-known processes to obtain electrospun fibers, the near-field electrospinning (NFES) and the far-field electrospinning (FFES). NFES has been used to pattern photosensitive nanofibers that can be readily converted into carbon nanowires interconnections for carbon-MEMS sensor applications [3] In this regard, the negative epoxy-based resins SU-8 series are commonly used as a carbon precursor, since they can be patterned into high aspect ratio three-dimensional (3-D) structures [4,5]. The negative epoxy-based resins SU-8 series are commonly used as a carbon precursor, since they can be patterned into high aspect ratio three-dimensional (3-D) structures [4,5] Properties, such as electrical and thermal conductivity of suspended carbon fibers produced with this technique and materials, have been recently studied, showing promising results for sensing and biosensing applications [6,7]

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