Abstract
The atomic structure and corrosion behavior of Fe87-xB13Nbx (x = 0, 7, 10 and 13) metallic glasses were investigated using various experimental techniques and simulations. The netlike (Fe, Nb)23B6 structure units, which took root in the Nb-contained amorphous matrix, emerged after annealing and raised markedly corrosion resistance of as-spun amorphous samples as cNb > 7 at.%, such as the occurrence of wider passive platform in the potentiodynamic polarization plots and the transformation from the porous holes to stable passive films on corrosion surfaces.
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