Abstract
Abstract In this study, we address heat-seal properties of poly (lactic acid) (PLA), blended with Poly (butylene adipate-co-terephthalate) (PBAT). The objective is to correlate blends crystalline structure and morphology to corresponding heat-seal of blends films. The SEM micrographs show a two-phase elongated morphology where stretched ellipsoids developed through elongational flow during the cast film process. To distinguish the effect of crystallization, we also prepared amorphous and crystalline PBAT films and then compared them to blends with PLA. Heat-sealed areas were created by putting film surfaces in intimate contact for 1 s at the pressure of 0.5 N/mm2 or Pa and in the temperature range of 70 to 140 °C. Thermal analysis shows that the crystalline structure of PBAT has a significant effect on shifting its heat-seal initiation temperature (Tsi) up to 20 °C. Regarding the blends, incorporation of PBAT as a dispersed phase lowers Tsi of blend samples. Here, gradual decrease in PBAT crystallinity caused by the hindering effect of PLA rigid molecules correlates with the shift in heat-seal initiation temperature. As mentioned above, elongated disperse morphology with higher aspect ratio of the dispersed phase compared to spherical dispersed domain, is formed through film cast process. This enhances the adhesion process by providing higher contact area. The blends also show higher toughness and better puncture resistance, which is an asset for flexible packaging applications and would enhance the mechanical performance of the seal layer.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
