Tailored design of three-dimensional rGOA-nZVI catalyst as an activator of persulfate for degradation of organophosphorus pesticides

Abstract

In this study, three-dimensional reduced graphene oxide aerogel (rGOA)-supported nanozero-valent iron (rGOA-nZVI) was successfully synthesized via tailored design and applied to activate persulfate (PS) to degrade three organophosphorus pesticides (OPPs; phorate, terbufos and parathion) in water and a historically contaminated soil. The results showed that loading nZVI nanoparticles on rGOA could prevent the aggregation of nZVI. rGOA-nZVI presented a better catalytic performance for PS activation to degrade the three OPPs than bare nZVI and rGOA, with degradation efficiencies of greater than 99.5% within 5 min. pH had negligible effects on the PS activated by rGOA-nZVI (rGOA-nZVI/PS). EPR measurements and radical quenching experiments showed that ·SO4- and ·OH were the main radicals responsible for OPP removal in the rGOA-nZVI/PS system. Furthermore, nine intermediates were identified, and the oxidation and scission of C-S-C, P-S/O and PS were the dominant degradation pathways of the three OPPs in aqueous solutions treated with rGOA-nZVI/PS. Additionally, rGOA-nZVI/PS achieved degradation efficiencies of 95.1% for phorate, 79.9% for terbufos and 89.1% for parathion in the contaminated soil, and the detected intermediates could be further degraded except triethylphosphate. Overall, this study provides practical knowledge for OPP removal by rGOA-nZVI/PS in wastewater and actual contaminated soil.