Abstract
AbstractTransition‐metal‐free, temperature‐controlled chemoselectivities of alkenylazaarenes and alkylazaarenes through t‐BuOK/18‐crown‐6 promoted functionalization reaction of methyl‐substituted N‐heteroarenes with primary alcohols has been established. Following the methodology, a variety of olefinated and alkylated N‐heteroarenes have been efficiently obtained. To understand the mechanism of the reactions, various control and kinetic experiments were carried out.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
