Abstract
To study the coherence of thermodynamic data of the AgNO3-LiNO3 -RbNO3 ternary system, phase diagram of the binary system AgNO3 -LiNO3 has been obtained between 303 and 550 K by direct and differential thermal analysis technique. This system is characterized by an eutectic point (25% mol. LiNO3 , 445±1 K) and a plateau due to the solid-solid transition in AgNO3 at 434±1 K. In the solid state the solubility of each component in the other seems to be nil or negligible (no more than a few percents). Using other thermodynamic data, the excess properties of the binary liquid (AgNO3 - LiNO3 ) were calculated at 623 K.
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