Systematics of zircon crystallisation in the Cretaceous Separation Point Suite, New Zealand, using U/Pb isotopes, REE and Ti geothermometry

Abstract

Plutonic zircons from the Cretaceous Separation Point Suite (SPS) were analysed by LA-ICPMS for U–Pb isotope ratios and trace element concentrations. Pooled 206Pb/238U ages range from 112 to 124 Ma. Cathodoluminescence imaging reveals minor inheritence and textural evidence of repeated dissolution and re-precipitation of zircon. Core and rim spot analyses, however, document zircon growth during extended periods of time (>2 myr). Protracted crystallisation histories for simple plutonic systems are inconsistent with generalised thermal constraints, which predict cooling below the solidus within <1 myr. Consequently, we conclude that the SPS granitoids sampled in this study were not emplaced rapidly but incrementally over extended time periods. Zircon Th/U and Zr/Hf ratios are positively correlated with crystallisation temperatures, consistent with crystallisation from evolving melts. However, highly variable trace element concentrations, along with temperature reversals are indicative of complex crystallisation histories involving continuous fractional crystallisation repeatedly punctuated by hotter, more mafic magma recharge. Normalised abundances of the redox-sensitive elements Eu and Ce in zircon vary systematically with degrees of whole rock differentiation, pointing to evolutionary trends in magmatic oxidation states coupled with feldspar crystallisation.