Abstract
Extensive single-configuration Dirac–Fock (DF) calculations (within the multiconfiguration DF method) with the inclusion of the transverse (Breit) interaction and QED corrections have been carried out on Mo and Pd to elucidate the structure of the Kβ2L0Mr satellite lines in their X-ray spectra. For each type of lines two theoretical spectra have been synthesized: one being a sum of the Lorentzian natural line shapes and the other one being a convolution of the sum of the Lorentzian natural line shapes with the Gaussian instrumental response. The obtained results can be used to determine the M-shell ionization probability in collisions via the theoretical analysis of Kβ2 spectra of Mo and Pd induced by different energetic light and heavy ions.
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