Abstract

The Eluxyl process achieves paraxylene separation to other xylenes and ethylbenzene. Eluxyl is a simulated moving bed process that requires a fine tuning to produce paraxylene at a very high level of purity, up to 99. 90%. A numerical model has been developed in parallel with the process. Objectives are to help tuning, to help design of additional equipment such as valves and mixing chambers and to test the so-called what if cases . According to these objectives, the model is planned to be modified many times in order to test different equipment, to evaluate what if casesor even to choose among different configurations. To match these requirements the numerical model has been developed under system approach. This paper presents the Eluxyl process and its mathematical model. Then, the ability of such a model to represent real units is illustrated through four examples. At first, the paper describes how slow opening and closing valves were modelled. The objective was to evaluate the requirement valves should meet about their time spent before total opening. Secondly, to emphasise the advantage of system approach modelling, the paper presents how a missing (under maintaining) valve could be modelled. In a third example, it is shown how a system approach model can help the design of real units. This paper explains how the different designs for the mixing chambers that equip the Eluxyl process have been modelled and tested. The key point is that the best design is selected on the simulated resulting performances of the unit-purity and yield. Finally a what if caseis presented. Here, a leaking valve is assumed and the net effect on purity and yield shows that requirement about valve leaking should be severe. All along this paper, we show how system approach modelling is powerful, fast, convenient and almost bug free compared with standard language programming.

Highlights

  • In a modern approach, mathematical and numerical models are developed along with the chemical reactor or separation unit design

  • We show how system approach modelling is powerful, fast, convenient and almost bug free compared with standard language programming

  • D Pavone and G Hotier / System Approach Modelling Applied to the Eluxyl Process

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Summary

INTRODUCTION

Mathematical and numerical models are developed along with the chemical reactor or separation unit design. Great and costly efforts are undertaken to enhance knowledge about thermodynamic adsorption laws or chemical reactions These are essential mathematical laws or equations that feed models, but it would be essential to model correctly the surrounding equipment such as valves, mixing chambers, etc. Sometimes, surrounding facilities are pretty well modelled and analysed, especially in 3D computed fluid dynamics (CFD) These models imply time-consuming simulations and design optimisation is performed over external criteria but the unit performance itself. The result is that tremendous effort could be engaged to improve equipment regarding an external criterion it has very little effect on the global unit performances Another aspect of modelling concerns the so-called “what if cases”. A “what if case” is presented about the occurrence of a leaking valve

Large Scale Industrial Continuous Liquid Chromatography
Model Description
A Typical Dynamic Simulation
REAL UNIT MODELLING
Model of Ideal Valve Cyclic Switching
Slow Valve Modelling
Reality Modelling
Why Mixing Chambers
Mixing Chamber Modelling
To pump info
Findings
CONCLUSION
Full Text
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