Abstract
The reactions of 3-acetoxy-3-aryl-2-methylene propionitriles 1 with ammonia yielded the corresponding diallylamines 3ZZ. The reaction of 1 with a primary allylamine or with ethylene diamine gave the diallylamine 11 or 13ZZ. The treatment of methyl 3-acetoxy-3-aryl-2-methylene propionates 2 with isopropylamine or ethylene diamine gave the allylamines 6EE or 14 and 15, but the reaction of 2 with ammonia gave only the triallylamines 4EEE in good yields.
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