Abstract
The rates of hydrolysis of 1-substituted 2,7,8-trioxabicyclo[3.2.1]octanes and 2,8,9-trioxabicyclo[3.3.1]nonanes (R = H, CH3, C6H5) have been determined at two temperatures in dioxan/water (60:40 by volume). These new results confirm the behaviour generally observed in the hydrolysis of orthoesters which have a favourable conformation to hydrolyze under stereoelectronic control.
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