Abstract
Preparation of compound NiI 2(CO)[P(CH 3) 3] 2 from Ni(CO) 2[P(CH 3) 3] 2 and iodine or NiI 2[P(CH 3) 3] 3 and carbon monoxide is presented. These are the first syntheses of dihalogen derivatives of nickel carbonyl. The diiodocarbonylbis(trimethylphosphine) nickel very likely has a trigonal bipyramidal structure with the two axial positions occupied by trimethylphosphine ligands.
Published Version
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