Abstract
The transmetallation reaction of group 14 metallacyclopentadienes, Cp 2EC 4R′ 4 (E = Ti, Zr, Hf; R′ = Ph, Me) with various halogermanes has been studied. The tetrahalides GeCl 4 and GeBr 4 undergo the E/Ge exchange reaction at room temperature, but the trihalides RGeCl 3 and dihalides R 2GeCl 2 (R = Me, Ph) are less reactive. Some germoles were found to be unstable. A phenyl group on the germanium atom stabilizes the 2,3,4,5-tetramethylgermoles with a GeH (HPhGeC 4Me 4) or GeCl bond (ClPhGeC 4Me 4).
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
