Abstract
Reactions of carbon nucleophiles with tricarbonyl(cyclohexadienyl)iron tetrafluoroborate are described. Acetaldehyde formed traces of the addition product and methyl vinyl ketone gave several products, but not the expected tricarbonyl5- exo-(2-oxobut-3-enyl)cyclohexa-1,3-dieneiron(0). The anion of nitromethane reacted with tricarbonyl(cyclohexadienyl)iron tetrafluoroborate to give tricarbonyl-5- exo-(nitromethyl)cyclohexa-1,3-dieneiron(0), which was reduced with zinc in acetic acid/hydrochloric acid to give tricarbonyl-5- exo-(aminomethyl)cyclohexa-1,3-dieneiron(0).
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