Abstract
AbstractRacemic 1′,4′‐dimethyladenosine was prepared according to a stereoselective sequence from 2,5‐dimethyl furan and vinylene carbonate. This sequence is short and efficient (nine steps) and relies on the desymmetrization of a meso diol, followed by the glycosylation of the anomeric position. The latter reaction was thoroughly studied, as it is the key step of the sequence, and very particular reactivity of the 1′,4′‐dimethylated sugars was observed. Secondary reactions took place according to original mechanisms and delivered original byproducts.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
