Synthetic studies on the seven- and eight-membered rings by the intramolecular Nozaki–Hiyama reaction of the allylic phosphates

Abstract

Synthetic studies on the seven- and eight-membered rings by the intramolecular Nozaki–Hiyama reaction of the allylic phosphates are described. The yield greatly depends on the structure of substrate; however, some complex substrates afforded desired products in high to excellent yield.