Abstract
Abstract Successive dialkylation of methyl acetoacetate with allylic functions 2 and 5, followed by oxidation, gave an α,β-unsaturated aldehyde 7. Intramolecular Michael addition of 7 to give a cyclopentanone 8, conversion to diester 9, and Krapcho decarbomethoxylation furnished methyl dl-jasmonate.
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