Abstract
Total synthesis and structural revision of onchitriol I, a γ-pyrone-containing polypropionate, are described. Comparison of onchitriols with peroniatriols indicated the striking similarities related to both C3-10 and C13-16 segments. Total synthesis of onchitriol I was reported. Structural revision of onchitriol I and stereochemical relevance with related natural products were also discussed.
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