Abstract
The overall relative reactivities of ethyl acetoacetate, diethyl malonate, acetylacetone, diethyl ethyl-, butyl-, acetyl-, and cyano-malonates, di-isopropyl malonate, ethyl cyano- and phenyl-acetates, ethyl diacetylacetate, triethoxy-carbonylmethane, and 1,1,2-triethoxycarbonylethane in their radical-induced addition reactions with oct-1-ene to give 1 : 1 adducts have been determined. Ethyl cyanoacetate (12·2) is by far the most reactive (diethyl malonate being taken as unity), while all are much less reactive than carbon tetrachloride (ca. 100).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Chemical Society B: Physical Organic
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.