Synthesized of a novel xanthate functionalized polypropylene as adsorbent for dispersive solid phase microextraction of caffeine using orbital shaker in mixed beverage matrices

Abstract

A newly synthesized xanthate functionalized chlorinated polypropylene (PP-Xa) was used as adsorbent for the orbital shaker based on dispersive solid phase microextraction (OS-DSPME) of caffein from several tea, coffee, energy drink, coca-cola and chocolate samples using UV-vis. spectrophotometer. Synthesized PP-Xa was characterized using Fourier Transform Infrared spectroscopy (FTIR-ATR) and nuclear magnetic resonance spectroscopy (1H NMR). Various parameters like pH, PP-Xa amount, extraction time, type of eluent and its volume were optimized. Linear range, detection limit (LOD), limit of quantification (LOQ), relative standard deviation (RSD), recovery values, and enrichment factor (EF) were found 90–1000 μgL−1, 27.3 µg L−1, 90 µg L−1, 1.9–2.6%, 98 ± 2%, and 167, respectively. Adsorption capacity of PP-Xa was found 271.9 mg g−1. Standard addition and reference method were used for confirm the accuracy of present method.