Abstract
A chromogenic 13-membered crown ether with a cis azo unit in the macrocycle has been obtained as a side product during the reduction of 1,5-bis (2′-nitrophenoxy)-3-oxapentane. The electrochemical properties of this compound have been studied by the voltammetric method. Its behaviour as an ionophore in ion-selective membrane electrodes has also been investigated. The X-ray structures of the new crown ether 3 and the parent compound 1 have been determined.
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